Hi Erin,
Honestly both databases will do the job just fine. I personally prefer Postgres.
Much more important is how you store the audio. While you could technically use a blob type column, it's really not ideal to be storing audio files which are "several hours long" in a database row. Instead consider storing the audio files in an object store (hosted options include backblaze b2 or aws s3) and persisting the key (which references that object) in your database column.