The one thing I wouldn't do is mix the two, different structures and ideas for how to do things
Taking a class in python already? I'd lean to Django Want to learn a language that will carry forward to a good paying job .net
Python is an excellent language, though it's often being replaced with things like go which uses a similar syntax
Over time you're going to learn many languages if you want to be a great programmer spend your time with one and dive deep, learn what makes it shine and what the draw backs are grow proficient with it and then consider learning something different so you can compare
Early on learning a single language at depth is more important than tinkering with several or learning any specific language
Good luck